Abstract
Recently, much attention has been paid to studies on nano- and microstructures formed by the self-assembly of cyclodextrins (CDs) in the fields of supramolecular chemistry and material science. CDs can adopt various types of assembly modes in aqueous solution, as well as crystal structures. Channel-type assemblies of γ-CD (γ-CDchannel) formed unique micrometer-sized cubes and rods. By using γ-CDchannel as a host, the inclusion of guest molecules dissolved in oils, which has been believed to be impossible, can be realized. Furthermore, γ-CDchannel showed excellent oil dispersion, and formed organogels in a variety of oils and organic solvents at ambient temperature. This article reviews the formation behavior and function of nano- and microstructures formed by the self-assembly of CDs.
