2009 年 34 巻 1 号 p. 51-54
We have investigated the physical properties and local atomic structure of LuFe2O4, a material belonging to the multiferroic system RFe2O4 (R: rare earths) which shows the new type of ferroelectricity owing to the charge ordering of Fe ions. Magnetic measurements showed the ferromagnetic ordering of Fe spins at ~230 K, as reported previously. From dielectric measurements, the dielectric constant (ε') of ~10000 was obtained at around room temperature. In addition, a peak of ε' was observed near the charge-ordering temperature (~330 K). The peak temperature was insensitive to the frequency of AC electric field; this behavior is different from that found in a previous study. The pair-distribution function analysis on a high-energy X-ray diffraction pattern revealed that LuFe2O4 has the systematic modulation of the local atomic displacement.