Transactions of the Materials Research Society of Japan
Online ISSN : 2188-1650
Print ISSN : 1382-3469
ISSN-L : 1382-3469
Chemically Cross-Linking Effects on the Sorption of Heavy Metal Ions to Hydrogels of Cyanobacterial Megamolecules, Sacran
Maiko Okajima-KanekoShinji MiyazatoTatsuo Kaneko
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2009 年 34 巻 2 号 p. 359-362

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Cyanobacterial polysaccharides, sacrans, are anionic megamolecules having extremely high molecular weights (Mw: 1.6 x 107). We confirmed by FT-MS analyses that sacran is composed of various partial structures such as continuous and combination structures of uronic acids and hexoses. We used highly swollen sacran gels (swelling degree: 700-800 times of dry weight) prepared by chemical cross-linking with diamines such as l-lysine. Sacran gels shrank and clouded in aqueous solutions of In and Gd ions and showed more than 100 times adsorption ratios of these metal ions compared with non cross-linked sacran presumably due to continuous uronic acids.
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© 2009 The Materials Research Society of Japan
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