X-ray Structure Analysis Online
Online ISSN : 1883-3578
ISSN-L : 1883-3578
Part 7
Crystal and Molecular Structure of a Cu(II) Complex with Macrocyclic Ligand of 10,12-dibromo-6-ethylcyanide-3,6,14,18-tetraazapentaicosa-1(25), 8(24),10,12,13,19,21,23-octaene-24,25-diol
Hamid GOLCHOUBIANDavod Sadeghi FATEH
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電子付録

2011 年 27 巻 p. 37-38

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The crystal structure of the title compound was determined by single-crystal X-ray diffraction. The compound crystallizes in a monoclinic system and was characterized thus: P21/n, a = 8.6189(2)Å, b = 17.9591(7)Å, c = 18.4009(6)Å, β = 102.2560(19)°, Z = 4, V = 2783.32(16)Å3. In the mono nuclear macrocyclic complex the copper(II) ion resides at the N(imine)2O2 coordination site, whereas the other compartment, N(amine)2O2, is occupied by a proton. The geometry around copper(II) is square-planar.
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© 2011 by The Japan Society for Analytical Chemistry
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