Crystal Structure of Isothiocyanato-N,N′-dimethyl-N,N′-bis(pyridine-2-ylmethyl)propane-1,3-diaminecopper(II) Perchlorate

Takashi YOKOYAMA; Masakazu YOSHISE; Shintaroh HASE; Ayumi KAWATE; Haruo AKASHI; Michio ZENKI

doi:10.2116/xraystruct.27.51

Part 9

Crystal Structure of Isothiocyanato-N,N′-dimethyl-N,N′-bis(pyridine-2-ylmethyl)propane-1,3-diaminecopper(II) Perchlorate

Takashi YOKOYAMA, Masakazu YOSHISE, Shintaroh HASE, Ayumi KAWATE, Haruo AKASHI, Michio ZENKI

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ジャーナルフリー
電子付録

2011 年 27 巻 p. 51-52

DOI https://doi.org/10.2116/xraystruct.27.51

詳細

抄録

The complex of an isothiocyanato-N,N′-dimethyl-N,N′-bis(pyridine-2-ylmethyl)propane-1,3-diaminecopper(II) perchlorate ([Cu(NCS)(LMe₂)]ClO₄) was prepared. Its crystal structure was determined by X-ray diffractometry. [Cu(NCS)(LMe₂)]ClO₄ crystallized in a triclinic system, and was characterized thus: P1, a = 9.257(3), b = 9.883(4), c = 11.806(5)Å, α = 89.638(12), β = 81.053(10), γ = 88.841(12)°, Z = 2, V = 1066.7(7)Å³. The crystal structure was solved by direct methods and refined by full-matrix least squares on F² to final values of R1 = 0.058.

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