Synthesis and Crystal Structure of Penthylenediammonium pentabromobismutate(III) [NH3(CH2)5NH3]BiBr5

Mohsen OULED MOHAMED SGHAIER; Mohamed ABDELHEDI; Slaheddine CHAABOUNI

doi:10.2116/xraystruct.28.1

Part 1

Synthesis and Crystal Structure of Penthylenediammonium pentabromobismutate(III) [NH₃(CH₂)₅NH₃]BiBr₅

Mohsen OULED MOHAMED SGHAIER, Mohamed ABDELHEDI, Slaheddine CHAABOUNI

著者情報

ジャーナルフリー
電子付録

2012 年 28 巻 p. 1-2

DOI https://doi.org/10.2116/xraystruct.28.1

詳細

抄録

X-ray studies on [NH₃(CH₂)₅NH₃]BiBr₅ show that it crystallizes in the orthorhombic P2₁2₁2₁ space group with the following unit-cell dimensions: a = 7.9580(4)Å, b = 14.0110(16)Å, c = 14.0960(14)Å. The structure was refined to R = 0.0492. It consists of penthylenediammonium cations and one-dimensional [BiBr₅]_n^2- polyanionic zig-zag chains composed of deformed BiBr₆ octahedra connected by two cis vertices. These chains are themselves interconnected by means of the N-H…Br hydrogen bonds.

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