Crystal Structure of (Cycloocta-1,5-diene)tris(hydrazine)hydrido-ruthenium(II) tetraphenylborate

Samson O. OWALUDE; Uche B. EKE; Ezekiel O. ODEBUNMI; Vladimir N. NESTEROV; Reinout MEIJBOOM; Neil J. COVILLE

doi:10.2116/xraystruct.28.29

Part 4

Crystal Structure of (Cycloocta-1,5-diene)tris(hydrazine)hydrido-ruthenium(II) tetraphenylborate

Samson O. OWALUDE, Uche B. EKE, Ezekiel O. ODEBUNMI, Vladimir N. NESTEROV, Reinout MEIJBOOM, Neil J. COVILLE

著者情報

ジャーナルフリー
電子付録

2012 年 28 巻 p. 29-30

DOI https://doi.org/10.2116/xraystruct.28.29

詳細

抄録

The salt [RuH(COD)(H₂NNH₂)₃][BPh₄] (2) (COD = cycloocta-1,5-diene and BPh₄ = tetraphenylborate) was prepared by reacting the polymeric species [{Ru(COD)Cl₂}_x] (1; x > 2) with hydrazine hydrate in refluxing ethanol. The obtained crystal was characterized by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P2₁/n with unit-cell dimensions a = 9.7449(8)Å, b = 32.881(3)Å, c = 18.6962(16)Å, β = 99.571(10)°, V = 5907.3(9)Å³ and Z = 8. The ruthenium has a distorted octahedral geometry with two formula units comprising two cations and two anions in the asymmetric unit.

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