Part 3
Synthesis and Crystal Structure of Bis[2-(2-imidazolinyl)phenolato]copper(II)
2018 Volume 34 Pages 11-12
Details
2018 Volume 34 Pages 11-12
The crystal structure of Cu(II) complex with 2-(2-imidazolinyl)phenolate was determined by X-ray crystallography. The title compound was synthesized by a reaction of Cu(NO3)2·3H2O and 2-(2-imidazolinyl)phenolate in methanol. The compound crystallized in the monoclinic space group P21/c and Z = 2 with cell parameters a = 9.2964(9)Å, b = 10.4722(10)Å, c = 8.8271(9)Å, β = 112.0280(10)°, V = 796.62(14)Å3. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0306 and 0.0844, respectively, for all 1943 independent reflections. In the crystal, a 2D sheet structure was formed by intermolecular hydrogen-bonds between the coordinating phenolate-O atom and a noncoordinating N–H bond.
