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有機合成化学協会誌
Vol. 72 (2014) No. 2 p. 181-182

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.72.181

Review de Debut

Dearomatization reactions of phenols have been useful and powerful reactions for construction of highly substituted three-dimensional structures seen in natural products. Recently, several groups have achieved the intermolecular asymmetric dearomatization reactions by oxidative protocol. Toste’s group reported asymmetric non-oxidative dearomatization of phenol derivative under the phase-transfer catalysis. Very recently, You’s group reported metal-catalyzed asymmetric alkylation of naphthols with high enantioselectivity.

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