Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
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Usable Optically Active Nitrogen-Based Tridentate Ligands for Asymmetric Catalysis
Hisao Nishiyama
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Keywords: bis(oxazoline), tridentate, asymmetric catalysis, hydrosilylation, cyclopropanation, face-selective coordination of olefins, conjugate reduction, reductive aldol reaction, diboration, alkynylation, hydrogenation
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2015 Volume 73 Issue 9 Pages 925-931

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Abstract

Looking back on a quarter-century or so, what kinds of discovery have been achieved in terms of asymmetric catalysis by use of optically active nitrogen-based tridentate ligands, 2,6-bis(oxazolinyl)pyridine (Pybox) and 2,6-bis(oxazolinyl)phenyl (Phebox).

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© 2015 The Society of Synthetic Organic Chemistry, Japan
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