Review de Debut
不活性末端アルケンの触媒的Markovnikov型ヒドロホウ素化反応
2018 年 76 巻 1 号 p. 55-56
詳細
2018 年 76 巻 1 号 p. 55-56
Regio- and stereoselective synthesis of organoboron compounds has great importance due to their wide applicability and high stereospecificity in many transformations such as Suzuki-Miyaura cross coupling reaction. Generally, hydroboration of unactivated terminal alkenes proceeds in anti-Markovnikov selective manner to produce linear products. In this short review, recent examples of catalytic Markovnikov hydroboration of unactivated terminal alkenes, and its application to asymmetric synthesis are described.
