Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Studies on the Utilization of 1, 4-Naphthoquinone. V
Derivatives from Naphthophenazine, Naphthosultum=phenazine and Brasanquinone
Akira INOUENobuhiko KUROKIKenzo KONISHI
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1958 Volume 16 Issue 11 Pages 603-606

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Abstract
Syntheses of nine kinds of yellow vat colors, (4), (5), (6)(C. I. Vat Yellow 27), (7a) or (7b), and (9)-(13), respectively, were made from condensation hydroxynaphthophenazine derived from 2-hydroxy-1, 4-naphthoquinone, sultazines and Naphthol-AS with 2, 3-dichloronaphthoquinone. Dyeing property and stability towards the light of these products have been investigated. The photosensitzed tendering was less in naphthosultumphenazine derivatives containing no furan ring and was more prominent in brasanquinone derivatives con taining furan ring. 6-Hydroxynaphthoquinone (2) can be used as a bottoming agent but the dyeing was rather light and its substantivity was 3/4 of Naphthol-AS.
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© The Society of Syhthetic Organic Chemistry, Japan
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