有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
主鎖中にピリジン核を有するポリアミド系新合成繊維に関する研究 (第2報)
アルコールを溶剤としたポリアミドの合成
岡太 昭室井 正生駒 一郎江村 幸彦石塚 修
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1958 年 16 巻 5 号 p. 255-257

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Condensation-polymerization of dimethyl isocinchomeronate and hexamethylenediamine was carried out by using m-cresol as a solvent in the preceeding experiment. This report deals with the possibility to see whether or not alcohols can be used as a solvent. The result indicated that methanol can be used as a solvent. The fiber thus obtained showed a slightly better characteristics that of the preceeding experiment and this may be attributed to an improvement of spinning technique. The product showing a slightly lower melting point, we have some problems to be determined later if it has the same chemical configuration as that obtained in the preceeding experiment. Also, it is necessary to improve somemore on the reacting conditions.

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