Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Studies on the Application of Trichloroiminocyanuric acid. II
Synthesis of Chloroanthraquinones
Toichiro ISHIIShigeru KANAIMasaaki YOSHIOKAAkitake MASUDA
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1959 Volume 17 Issue 9 Pages 545-549

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Abstract
An application of trichloroiminocyanuric acid for substitution of sulfonyl group in anthraquinone-α-sulfonic acid and anthraquinone-β-sulfonic acid by chlorine to give corresponding chloroanthraquinones has been made.Trichloroiminocyanuric acid was added portionwise into potassium or sodium anthraquinonesulfonate in 2.1% hydrochloric acid at 95-98°C to give α-and β-chloroanthraquinone with 95% and 93% yield, respectively.
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© The Society of Syhthetic Organic Chemistry, Japan
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