有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
インジゴおよびチオインジゴのクロルメチル化
中沢 昌
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ジャーナル フリー

1963 年 21 巻 1 号 p. 53-58

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抄録
Chloromethylation of indigo and thioindigo in concentrated sulfuric acid and sym-dichlorodimethyl ether or aluminiumchloride-pyridine mixture and sym-dichlorodimethyl ether yielded mono-, bis- and trichloromethyl compounds from the former and mono- and bis-chloromethyl compounds from the latter. In the case of indigo, the chloromethyl groups were entered into 5, 5' and 7-positions. These chloromethyl compounds gave pyridinium salts and isothiuronium salts, and their dyeing abilities were explained.
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