In planetary exploration missions, which require long-term operation, dinitrogen tetroxide containing 3wt% nitrogen monoxide (MON-3) is commonly used as the oxidizer in bipropellant propulsion systems. While MON-3 offers the advantage of being storable at ambient temperature, it has been reported to react with stainless steel used in piping materials, locally increasing the iron concentration and potentially causing malfunctions. Most previous studies have attributed such issues to flow path blockage caused by dissolved iron. However, in Mission “HAYABUSA2,” a phenomenon was observed that could not be sufficiently explained by this mechanism alone. In-flight data from Mission “HAYABUSA2” revealed impulse bit reduction, suggesting that the elevated iron concentration in MON-3 may have degraded its reactivity with hydrazine (N2H4). To investigate the mechanism, we conducted droplet tests using N2H4 droplets and a pool of MON-3, and measured the luminescence of OH* radicals in the combustion field. The results showed that although the peak combustion intensity remained unaffected by the increased iron concentration, the ignition delay time became longer, and the time to reach the peak intensity was extended. Based on these findings, we propose the mechanism underlying the observed impulse bit reduction.
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