The objective of this work was to use coal as the raw material to prepare activated coke (AC) catalysts of industrial-scale size for SO
2 removal from flue gas and to find the optimal additives and preparation methods. Results showed that activated coke with metal loaded was a suitable method, and that the activated coke catalysts, prepared by loading with CoCl
2 or CaCO
3 and finally calcining at 700°C, exhibited the best desulfurizing property with a sulfur retention of about 98.6mg-SO
2/1g-AC at a reaction temperature of 80°C. Also, the effects of H
2O content in the flue gas, reaction temperature and space velocity on the desulfurizing property were investigated to determine optimum operating conditions. An H
2O content of about 10% was appropriate for catalysts in this work. In the temperature range 70∼110°C, the catalyst showed good performance for SO
2 removal and was gradually deactivated at temperatures above 110°C. Space velocity exhibited an optimal value of 800 h
-1. The kinetic behavior varied with space velocity and the desulfurizing property was controlled by adsorption at space velocities below 800 h
-1, and controlled by catalytic reaction at space velocities above 800 h
-1.
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