In order to study the relation between thermal and electrical conductivities of alloys at low temperatures, the conductivities of Ni-Cu alloys were measured at -195° with an improved apparatus. According to the present results, the Wiedemann-Franz-Lorenz law does not hold especially at low temperatures and for concentrated alloys, and, the general relation λ=λg+λm=λg+
ZmkT+
_??_(T)k2 holds, which can interprete the results represented by the following experimental formulas, i.e. for dilute alloys ω=ω
0+
p/ZmT, ω
0=
-_??_(T)/Zm2T2, and for concentrated alloys λ=λg+
ZmkT where
Zm is the Lorenz-ratio 5.8×10
-9 (cal
Ω deg
-2) theoretically deduced for the metallic part. The increase of experimental value of Lorenz-ratio for alloys at low temperatures was also explained from the general equation. The relations between λ or k and concentration of the same alloys were also studied.
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