The thermoplastic Polyimide (PI) is a kind of super engineering plastic, and it is used in the advanced field with Carbon Fiber Reinforced Polyimide (CFRPI). Therefore, they are required long term reliability. On the other hands, the physical aging phenomenon must occur to PI and CFRPI under the glass transition temperature. This phenomenon makes the state of materials close to the equilibrium state, and the polymer chains will be hard to move. And it is the physical aging acts as the hardener on creep behavior, and it acts as non-linear factor on the visco-elastic theory. It is therefore, we have to reveal the effect of physical aging for the long term reliability. In this study, PI and CFRPI controlled various physical aging state were prepared. The purposes were to evaluate the progression of physical aging, and to investigate the effect of physical aging on thermal and visco-elastic properties. As a result, the progression of physical aging caused the endothermic peak at glass transition increasing on DSC analysis, the activation energy by the time-temperature superposition principle increasing and the aging shift factors calculated by the master curve for the heat treatment time increasing. Their values have the same tendency on each other, and they have the linear relationship between these values. And the value of DSC analysis can calculate the effect of physical aging easily.
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