In the present work, experiments on the non-thermal plasma decomposition of isobutanol, which is a particularly malodorous volatile organic compound, were conducted by using a wire-in-tube plasma reactor in an N
2-O
2 atmosphere (N
2: balance gas). The initial concentration of isobutanol was fixed at 100 ppm and the concentration of O
2 and the relative humidity ranged from 0-75vol% and 0-60%, respectively, at a total gas flow rate of 200×10
−6 m
3· min
−1 and a reaction temperature of 298K. The influence of coexisting O
2 and H
2O on the plasma decomposition of isobutanol was studied on the basis of the experimental results obtained.
As a result, under these experimental conditions, it was found that the ratio of decomposition of isobutanol decreased with an increase in O
2 concentration and increased with an increase in relative humidity. An isobutanol decomposition ratio of 100% was obtained in a reaction atmosphere of O
2 20vol% and a relative humidity of 60% at a specific input energy higher than 0.90MJ · m
−3. From this finding, it is thought that OH radicals produced from the plasma decomposition of H
2O enhanced the plasma decomposition of isobutanol.
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