The use of supercritical water to recover iron oxides from oily mill sludge emitted by the steel industry was examined. Using supercritical water oxidation treatment, more than 95% of the organic materials contained in the sludge were removed, and they could be degraded completely to CO
2. In addition, there were indications that iron oxides catalyzed the oxidation reactions of organic materials. Using supercritical water treatment without oxygen, some of the organic materials were removed from the sludge. Iron oxides contained in the sludge were oxidized to Fe
2O
3 with the existence of oxygen in an amount in excess for the oxidative degradation of organic materials. On the other hand, reductive materials were formed when the amount of oxygen was less than the stoichiometric amount by partial oxidation of organic materials, and it was possible to reduce Fe
2O
3 to Fe
3O
4. These results suggest that the efficiency of treatment and the conditions of recovered iron oxides are influenced by the interactions between iron oxides and organic materials in supercritical water, and show the prospect of using supercritical water as a novel method for the recovery of inorganic resources from organic-inorganic mixed wastes.
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