Pyrolysis and combustion experiments of dried sewage sludge were conducted using an electrically heated drop furnace to elucidate NOx formation/destruction characteristics. When the dried sewage sludge was fed into the drop furnace, the particle temperature rose rapidly and the particles swelled. The char particle structure became balloon-like. Regarding NOx formation, both NO and N
2O were formed during combustion. After N
2O was generated in the flame, NO was produced because N
2O was destroyed by H radicals formed by CO oxidation. Although conversion of fuel-N into N
2O decreased with increased furnace temperature, conversion of fuel-N into NO increased. The N
2O conversion ratio of the dried sewage sludge was higher than that of the sample coal because the dried sewage sludge emits more HCN, which more readily produces N
2O.
View full abstract