In order to recover abrasive grains from waste grinding wheels (phenolic resin and abrasive grains), combustion/thermal degradation of waste grinding wheels was carried out in both an O
2/Ns
2 (20/80%) atmosphere and a steam/N
2 atmosphere at 800°C in a batch reactor. In the present study, two kinds of grinding wheels were used : sample A consisted of Al
2O
3/SiC/Phenolic resin (70/20/10 wt%), and sample B consisted of Al
2O
3/Phenolic resin/FeS
2/K
2SO
4/KCl/CaO/Glass fiber (53/7/25/7/2/2wt%) .
Through combustion at oxygen ratios of 1.1-2.6, carbons of the phenolic resin in both samples A and B were converted almost completely to CO
2 in 5-20 minutes. It was confirmed that the main abrasive grain component, Al
2O
3, could be recovered from the solid residues. In addition to CO
2 generation, gases such as CO, lower-hydrocarbons, and NOx were detected during the thermal degradation of sample A in an O
2/N
2 atmosphere. In the thermal degradation of sample B, SO
2 and HCl were detected among gases such as CO
2 and CO. Behaviors of CO
2 and CO formation were observed in the thermal degradation of sample B in the stream/N
2 atmosphere similar to those in the thermal degradation in the O
2/N
2 atmosphere. In this case, lower-hydrocarbons, CS
2 and H
2S were detected along with CO
2 and CO. However, the main abrasive grain, A1
2O
3, was found to be recoverable through thermal treatment in the steam/N
2 atmosphere.
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