As one of the new means of safe treatment of polyvinyl chloride wastes, reaction conditions of dechlorination in hot water at up to 400°C were investigated. Results may be summarized as follows.
1) Dechlorination can be done by a one hour reaction in hot water at sub-critical conditions over 300°C, and by a 20 hour reaction at 250°C, with presence of metal iron, or in alkaline solution.
2) With metal iron, the dechlorination reaction is dominant and decomposition reaction seems not to proceed, so that the residue is a dechlorinated solid.
3) In alkaline solution, dechlorination and hydration reactions proceed simultaneously so that the main reaction products are water-soluble or in-soluble liquids, and little solid residue remains.
4) With metal iron in alkaline solution, the dechlorination reaction is dominant, but at supercritical conditions decomposition reaction easily occurs.
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