Volatile organic chlorinated compounds have been used in large quantities because they have various useful properties industrially. Some of them, however, have been proved to be carcinogenic or ozone depleting substances. Optimal incineration conditions have been investigated for liquid waste containing 1, 1, 1-trichloroethane (C
2H
3Cl
3), carbon tetrachloride (CCl
4) . Incineration tests with varying mean residence time, in which the temperature of incinerator was about 950°C, were carried out in a commercial field plant. In spite of long and short mean residence times (9.1 sec vs. 1.8 sec), there was little difference in DBEs (destruction and removal efficiencies) of C
2H
3Cl
3 and emissions of PICs (products of incomplete combustion) . Additionally, incineration tests with varying temperature of incinerator were carried out in a laboratory-scale incineration plant. In higher temperature conditions, above 800°C, DREs of C
2H
3Cl
3 and CC1
4 exceeded 99.999%. But in the lowest temperature condition, about 700°C, DREs decreased and some PICs increased greatly. When experimental DREs were compared with theoretical DREs, which were calculated with gas phase reaction rate as rate-determining step, experimental DREs of C
2H
3Cl
3 were much lower than theoretical DREs. It was thought that these results were due to not considering the evaporation rate of drops formed when liquid waste was fed to the incinerator. Therefore, atomizing conditions were considered to be one of the important factors of C
2H
3Cl
3 thermal destruction. However, DREs of CCl
4 were higher than theoretical DREs. Waste was fed with liquefied petroleum gas to the incinerator, so the atmosphere in the incinerator was hydrogen-rich. Hence, H/Cl the ratio of waste was considered to be one important factor in CCl
4 thermal destruction.
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