Nowadays, in manufacturing industry, "Enthalpy balance" is widely used for the control of energy saving, but it seems to be not always effective and adequate when we refer carefully to the 2nd law of thermodynamics. Moreover, in such industry as ammonia synthesis, which involves many high pressure processes, we can not comprehend exact value of the compressing power of material gases when only enthalpy balance is used.
In this report, we tried to employ so called "Availability, " B=H-T
0S, as a function which consistently indicates scale of energy utility from material coke to final product in ammonia manufacture and aimed at making clear the actual losses of energy in each process. As a comparison, the same kind of analysis of ammonia production by water electrolysis is shown here.
All of the results of these calculations are indicated both in tables and figures.
View full abstract