The crystal structure of yeatmanite [Mn
5Sb
2]
VI[Zn
6Mn
4(Si
3.8Fe
0.23+)]
IVO
28; P-1,
a = 5.443(3),
b = 11.683(5),
c = 9.134(4)Å, α = 92.06(4), β = 101.19(4), γ = 76.34(4)°, Z = 1] from Franklin, New Jersey, has been refined to an R = 0.100 using 1881 reflections. The structure scheme proposed by Moore
et al. [(1916);
Neues Jahrb. Abh.,
127, 47–61] was proved to be correct. The octahedral sheet consisting of 5Mn and 2Sb is sandwiched by the upper and the lower tetrahedral sheets consisting of Zn
3Mn
2Si
2, respectively. Along the
a-axis, there are two rows of Si tetrahedra, one of which is surrounded by 4ZnO
4 and 2MnO
4, and the other by 3ZnO
4 and 3MnO
4. A small portion of the latter is replaced by trivalent iron. The mean distances of M–O are as follows: Sb
VI–O 2.00 Mn(1)
VI–O 2.24, Mn(2)
VI–O 2.19, Mn(3)
VI–O 2.22, Mn(4)
VI–O 2.12, Mn(5)
IV–O 2.08, Zn(1)
IV–O 2.03, Zn(2)
IV–O 1.95, Zn(3)
IV–O 1.99, Si(1)
IV–O 1.64 and Si(2)
IV–O 1.66Å.
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