Mineralogical Journal
Online ISSN : 1881-4174
Print ISSN : 0544-2540
ISSN-L : 0544-2540
Volume 9, Issue 7
Displaying 1-5 of 5 articles from this issue
 
  • Satoshi MATSUBARA, Akira KATO, Kozo NAGASHIMA
    1979 Volume 9 Issue 7 Pages 383-391
    Published: 1979
    Released on J-STAGE: March 31, 2007
    JOURNAL FREE ACCESS
    Iwakiite, Mn2+(Fe3+, Mn3+)2O4, is tetragonal, space group P42nnm, a 8.509, c 8.534Å, Z=8, and is found in rhodonite-quartz ore from the regionally metamorphosed manganese ore deposit of the Gozaisho mine, Fukushima Prefecture, Japan.
    Wet chemical analysis by K. N. gave MnO 30.34, MgO 0.61, Mn2O3 22.70, Fe2O3 44.42, Al2O3 0.32, SiO2 0.47, TiO2 0.30, SrO 0.04, Na2O 0.02, K2O 0.02, total 99.24%, corresponding to (Mn2+0.982Mg0.035)Σ=1.017(Fe3+1.277Mn3+0.660Si0.018 Al0.014Ti0.009)Σ=1.978O4 on the basis of O=4, or ideally Mn2+(Fe3+, Mn3+)2O4, where Fe3+:Mn3+=2:1. The strongest X-ray powder diffractions are 4.929(30) (111), 3.016(40) (202, 220), 2.570(100) (113, 311), 1.640(30) (333), 1.509(35) (404), 1.506(40) (440). They are similar to but distinct from those of jacobsite due to splitting of (404)–(440).
    It is opaque. Colour is greenish black, lustre metallic. Streak is black. No cleavage. Density (g/cm3) 4.85 (meas.), 4.89 (calc.). Strongly magnetic. It is optically anisotropic. The reflection colour in air is olive grey like jacobsite without discernible reflection pleochroism. Between crossed polars the colour changes from yellowish to brownish grey.
    The name is for the city name Iwaki, in which the locality is situated. Type material is deposited in National Science Museum, Shinjuku, Tokyo, Japan.
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  • Toshio KATO, Yasunori MIÚRA, Morimasa YOSHII, Kenjiro MAEDA
    1979 Volume 9 Issue 7 Pages 392-408
    Published: 1979
    Released on J-STAGE: March 31, 2007
    JOURNAL FREE ACCESS
    The crystal structures of 1M-kinoshitalite and four 1M-manganese trioctahedral micas, all from Nodatamagawa mine, Iwate Prefecture, have been refined. Effect of cation substitutions in these structures is discussed based on correlations among structural and chemical compositional parameters. It was found that the ‘chemical expansion’, the expansion in the Mg octahedron by the substitution of Mn2+ for Mg, affects cell parameters and geometry of the tetrahedra and other polyhedra.
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