Natural pyrrhotite is classified into three types on the basis of its temperature dependency of magnetism. First, the peak-type pyrrhotite has the weakest magnetism among the three types, and its intensity of magnetization is within the range of 1.2 gausses to 18.8 gausses (the applied magnetic field
H=10, 600 Oe.). The magnetization
I of the peak-type pyrrhotite increases linearly with the increasing magnetic field
H. A characteristic of this type is that the
I-T curve has a single sharp peak at 220°C. Secondly, the magnetization of the weiss-type pyrrhotite having the strongest magnetism among the three reaches a saturated value within about 10, 000 Oe. of applied magnetic field, and its saturation magnetization lies between 103 gausses and 118 gausses. The
I-T curve of this type of pyrrhotite shows the tendency of that of the ordinary Weiss-type, and its Curie point is at 305°C. Thirdly, the mixed-type pyrrhotite has an intermediate tendency in intensity of magnetization, the magnetization curve and the
I-T curve each coming between those of the peak and the Weiss types.
A close relation exists among the above-mentioned magnetic properties of pyrrhotite, its chemical composition which lies between FeS
1•104 and FeS
1•158, and its crystal structure. It has been shown that the Weiss-type pyrrhotite and a part of the mixed-type one (
I>100 gausses) have the Bertaut's monoclinic structure.
The
I-T curves in the cooling process of the peak-type and the mixed-type pyrrhotites do not coincide with those of the heating process. This phenomenon results from an increase of the atomic ratio of sulphur of pyrrhotite in the latter process.
before and after heat treatment. The most appropriate explanation for this phenomenon may be to postulate some increment of the atomic ratio of sulphur of pyrrhotite due to the diffusion of free sulphur, which has been formed in connection with the surface oxidation of pyrrhotite at room temperature, into the inner part of the grains in the heating process.
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