Mineralogical Journal
Online ISSN : 1881-4174
Print ISSN : 0544-2540
ISSN-L : 0544-2540
13 巻, 2 号
選択された号の論文の5件中1~5を表示しています
 
  • Toshio KATO
    1986 年13 巻2 号 p. 53-64
    発行日: 1986年
    公開日: 2007/03/31
    ジャーナル フリー
    The crystal structure of yeatmanite [Mn5Sb2] VI[Zn6Mn4(Si3.8Fe0.23+)] IVO28; P-1, a = 5.443(3), b = 11.683(5), c = 9.134(4)Å, α = 92.06(4), β = 101.19(4), γ = 76.34(4)°, Z = 1] from Franklin, New Jersey, has been refined to an R = 0.100 using 1881 reflections. The structure scheme proposed by Moore et al. [(1916); Neues Jahrb. Abh., 127, 47–61] was proved to be correct. The octahedral sheet consisting of 5Mn and 2Sb is sandwiched by the upper and the lower tetrahedral sheets consisting of Zn3Mn2Si2, respectively. Along the a-axis, there are two rows of Si tetrahedra, one of which is surrounded by 4ZnO4 and 2MnO4, and the other by 3ZnO4 and 3MnO4. A small portion of the latter is replaced by trivalent iron. The mean distances of M–O are as follows: SbVI–O 2.00 Mn(1)VI–O 2.24, Mn(2)VI–O 2.19, Mn(3)VI–O 2.22, Mn(4)VI–O 2.12, Mn(5)IV–O 2.08, Zn(1)IV–O 2.03, Zn(2)IV–O 1.95, Zn(3)IV–O 1.99, Si(1)IV–O 1.64 and Si(2)IV–O 1.66Å.
  • Naoya IMAI, Jae-Ill CHUNG
    1986 年13 巻2 号 p. 65-74
    発行日: 1986年
    公開日: 2007/03/31
    ジャーナル フリー
    The first Korean ikunolite is found in Zn–Pb–Ag skarn ores from Wolam deposit of the Yeonhwa 1 mine, Republic of Korea. The average of ten microprobe analyses on nine discrete grains is: Bi 84.48, Pb 4.87, Ag 0.09, S 10.30, Se 0.01, Te 0.13, Total 99.88 wt.%, yielding the empirical formula (Bi3.76Pb0.22Ag0.013.99(S2.99Se0.00Te0.01) Σ3.00 (basis: S + Te + Se = 3.00). The identification is substantiated by X-ray micro-diffraction and ore microscopic studies including the reflectance measurement and etch test using 20% FeCl3 solution.
    Informations due to the present finding are: 1) the first occurrence in skarn ores, 2) non-essential nature of Se and possibly Te, and 3) direct co-existence with galeno-bismutite (PbBi2S4), bismuthinite (Bi2S3) and native bismuth (Bi) to encompass the composition of the present ikunolite in the ternary system Pb–Bi–S, suggesting the necessity of such off-system component as Ag for the observed association.
  • Surinder SINGH, Dilbag SINGH, A. S. SANDHU, H. S. VIRK
    1986 年13 巻2 号 p. 75-85
    発行日: 1986年
    公開日: 2007/03/31
    ジャーナル フリー
    The etched track work on samples cut from different planes of apatite crystal is carried out in order to study the anisotropic etching behaviour of the crystal. The variation of the etched pit characteristics with crystallographic orientations is observed. The effect of the anisotropic etching on the age determination is reported. The etching conditions are determined for different planes using HNO3 as the track etchant.
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