In order to obtain a fluorescent material that emits white light with a high color rendering property, an attempt was made to synthesize a phosphor based on strontium aluminate as the matrix crystal. Synthesis in an air atmosphere resulted in fluorescent materials based on a mixed phase of SrAl12O19 and Sr4Al14O25. By irradiating the obtained mixed phases with an excitation wavelength of 365 nm, red luminescence derived from Eu3+ ions was simultaneously obtained from SrAl12O19 and blue-green luminescence derived from Eu2+ ions from Sr4Al14O25. The Eu2+ ions in Sr4Al14O25 were obtained by a reduction reaction during calcination in an air atmosphere. The obtained luminescence color varied from red to white depending on the synthesis conditions, and (0.357, 0.348) was obtained as the chromaticity coordinate closest to the white point. Two types of fluorescent materials based on strontium aluminate matrix crystals were obtained in a single synthesis, and white luminescence with excellent color rendering was obtained by simultaneous luminescence.
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