Ammonium nitrate is the most consumed chemical fertilizer in agricultural fields. Due to its easy accessibility and economic value, its physicochemical properties are also utilized in the explosive industry. However, this feature has made it preferable for anti-social purposes. To prevent this, researchers have focused on the addition of various chemicals to reduce the enthalpy of ammonium nitrate to the production process of ammonium nitrate.
In this study, the most important parameter of ammonium nitrate for the plant to reduce nitrogen concentration and storage conditions to minimize the triggering of caking phenomena and does not affect the heavy metal uptake of the plant by adding diboron trioxide, potassium fluoride and potassium tetrafluoroborate, enthalpy value, with significantly reduced results, calorimetry tests was also supported.
As determined from the results of instrumental analysis, it was observed that ammonium nitrate significantly increased in the crushing strength even when diboron trioxide, potassium fluoride and potassium tetra fluoroborate, which were used during the study, were added (<0.03 %). It can be stated with the results obtained in this case that the tendency of ammonium nitrate to be degraded decreases and its storage life increases. Although the crushing strengths are similar to each other when all three chemicals are added alone, it was found that when all three chemicals are added to the same reaction medium, it has the highest crushing strength.
However, due to the low concentrations of boron content, which is a heavy metal of the chemicals used, it can be seen from the peak heights in the ammonium nitrate content in anion and cation analysis in ion chromatography. In this respect, the nitrogen concentration of ammonium nitrate is not affected in terms of agricultural use, as can be seen in nitrogen analysis. When DSC analysis was performed as calorimetric value, it was found that boron compounds had a significant effect on reducing the enthalpy of ammonium nitrate. Thus, it was found that with the addition of all three chemicals, there was no exothermic peak in combustion reactions, so the tendency to detonate was significantly reduced. In order to analyze another parameter affecting the detonation reaction, surface porosity analysis was performed with an electron microscope. It has been found that boron compounds reduce surface porosity, thereby reducing detonation enthalpy, however, on the surface of the ammonium nitrate, where all three compounds are added together, the smallest and least number of porosity is obtained compared to the ammonium nitrate surface, where each compound is added alone.
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