We evaluated proton budget and soil acidification rate in a forested watershed in Jiulianshan, southern China. In this watershed, atmospheric deposition of H
+ , NH
4+ , Ca
2+, SO
42- (400, 351, 299 and 876 eq/ha/yr, respectively) were higher than those of other solutes (< 200 eq/ha/yr), and origin of these substances may be southwestern or northem China. Soil acidification rate was 2562 mol/ha/yr, and was not high. The most important process for the soil acidification was the base cation export from the watershed by “ion exchange and weathering” in the soil, mainly owing to the net loss of Mg
2+ (830 eq/ha/y). However, the high retention of H
+ , NH
4+ and SO
42- in this watershed also acidified the watershed soil (399,321 and 723 eq/ha/yr, respectively), and the SO
42- retention had a major influence on soil acidification. When the proton budget was evaluated for the soil compartment, the importance of anion retention was suggested. Although the watershed soil is becoming more acidic, the stream water was not acidic. However, continuous atmospheric deposition of acidifying substances and further acidification of the soil may lower pH in this stream.
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