Glucogenkwanin, C
22H
22O
11⋅2H
2O, faint yellow needles, m.p. 273-274°, was isolated from the bark of
Prunus verecunda (Koidz.) Koehne and two kinds of
P. Jamasakura variety (Japanese hill cherry). From the bark of
P.
Lannesiana variety (double-petalled species), sakuranin was obtained. When hydrolyzed with 5% H
2SO
4, glucogenkwanin gave genkwanin and glucose. By the methylation of glucogenkwanin with dimethyl sulfate and 30% KOH solution and following hydrolysis of the methylated product with 5% H
2SO
4, apigenin-7, 4′-dimetyl ether, m.p. 174-174.5°, was obtained. Glucogenkwanin, therefore, is genkwanin-5-glucoside.
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