Stress corrosion cracking (SCC) tests of commercial carbon steels were conducted both in a liquid ammonia saturated with NH
4CO
2NH
2 at 30°C for 500 h and in a field liquid ammonia. H
2S cracking tests for the same specimens were also carried out. The results obtained are as follows:
(1) In the liquid NH
3-NH
4CO
2NH
2 SCC of quenched steels occurs if the hardness of the specimens is high, and the increase of carbon content accelerated SCC. This result is similar to that in H
2S cracking tests.
(2) In a liquid NH
3 SCC of quenched steels tends to occur if the content of alloying elements in the steels is high, even though their hardness is low. Nickel in the steels has the most remarkable effect on SCC and many corrosion cracks in the liquid NH
3 were observed on the steels containing Ni.
(3) Tempering above 300°C after quenching decreases markedly the susceptibility to SCC of all the types of steels in the liquid NH
3-NH
4CO
2NH
2.
(4) The hydrogen permeability into the steel is increased by the addition of NH
4CO
2NH
2 to liquid NH
3, and the susceptibility to SCC of each steel in the liquid NH
3-NH
4CO
2NH
2 is similar to that to H
2S cracking. Therefore, the propagation of cracks in the steel seems to be due partly to hydrogen emblitlement in the liquid NH
3.
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