The direct analysis of solid metal samples by inductively coupled plasma emission spectrometry has been investigated. The aerosol generator (AG) by a low voltage spark discharge was used for vaporization of metal samples, and the aerosole was introduced into plasma through the aerosole cyclone, in which fine metal particles were selected from larger particles or gathering ones, in order to make aerosole uniform. An optimum electrode gap of AG was 5.0 mm, taking into account of the electrode durability and the reproducibility of spectral intensities and spectral intensity ratios. As for the argon flow rate, when the flow rate of carrier gas and that of acceralating gas were in total 11×10
3 cm
3/60 s (111/min), good analytical results were obtained, and when the ratio of the both was 2.5×10
3 cm
3/60 s: 8.5×10
3 cm
3/60 s, the reproducibility of spectral intensity ratios was best. The optimum observation height of plasma was 12 mm from the coil. The low alloy steels were analysed. The calibration curves (NBS 1161∼1168) for P, S, As, Mo, Co, Ni, Si, Mn, Cr, V, Nb, Cu, Ti, Zr and Al were all straight, while those obtained by the quantovac spectrometer were curved except for P, S, Co, Nb, Zr and Al. The precision and the accuracy were satisfactory for the routine analysis of alloy steels.
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