Magnesiorowlandite, Y
4(Mg,Fe)(Si
2O
7)
2F
2, a Mg–analogue of rowlandite–(Y), was found in a pegmatite at Souri Valley,
Komono
, Mie Prefecture, central Japan. The mineral occurs as aggregates composed of gray massive and white powdery parts. The aggregates are up to 1 cm in diameter scattered in the pegmatite. The mineral is associated with quartz, albite, K–feldspar, muscovite, allanite–(Ce), gadolinite–(Y), and ‘yftisite–(Y)’. It is transparent and gray to white in color with a vitreous to oily luster. The streak is white and cleavage is not observed. The Mohs hardness is 5 to 5½. The calculated density is 4.82 g/cm
3. It is biaxial negative and refractive indices are α = 1.755 (5) and γ = 1.760 (5) with non–pleochroism. Electron microprobe (WDS) analysis gave SiO
2 28.61, FeO 2.94, MnO 0.35, MgO 2.77, CaO 0.03, Y
2O
3 36.02, La
2O
3 0.29, Ce
2O
3 2.64, Pr
2O
3 0.64, Nd
2O
3 4.72, Sm
2O
3 2.82, Gd
2O
3 4.45, Tb
2O
3 0.69, Dy
2O
3 4.87, Ho
2O
3 0.50, Er
2O
3 1.64, Tm
2O
3 0.34, Yb
2O
3 2.02, Lu
2O
3 0.69, ThO
2 0.24, F 4.56, –F
2=O 1.92, total 99.91 wt% (average of 16 analyses), and led to the empirical formula, (Y
2.71Nd
0.24Dy
0.22Gd
0.21Ce
0.14Sm
0.14Yb
0.09Er
0.07Pr
0.03Tb
0.03Lu
0.03Ho
0.02Tm
0.02La
0.01Ca
0.01Th
0.01)
∑3.98(Mg
0.58Fe
0.35Mn
0.04)
∑0.97Si
4.00O
13.97F
2.03 on the basis of O + F = 16. The mineral is triclinic,
P1,
a = 6.527(6),
b = 8.656(9),
c = 5.519(5) Å, α = 99.09(8), β = 104.17(7), γ = 91.48(8)°,
V = 297.9(5) Å
3, Z = 1. It is non–metamict, and the strongest lines in the powder XRD pattern [
d(Å) (
I/
I0)
hkl] are 4.95 (33) 110; 3.64 (37) 0
21; 3.54 (38) 1
11; 3.08 (100)
201, 021; 2.92 (26) 21
1, 210; 2.68 (32) 11
2; 2.65 (26)
130, 0
12, 002; 2.63 (28)
220. The crystal structure was determined and refined to
R1 = 0.0736 for 1645 reflections with
I > 2σ(
I) of single crystal XRD data. In the crystal structure, the Si
2O
7 group, together with (Mg,Fe)O
4F
2 octahedron, connects the 7–coordinated and 8–coordinated REEs polyhedra to form the 3–dimensional structure.
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