Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Triterpenoid Chemistry. VI. Lycopodium Triterpenoid. (5). The Structures and Stereochemistry of Serratriol, 21-Episerratriol, and Lycoclavanol
津田 喜典佐野 武弘森本 明畠中 稔犬伏 康夫
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1974 年 22 巻 10 号 p. 2383-2395

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The structures of triterpenoid-triols, serratriol, 21-episerratriol, and lycoclavanol, isolated from Lycopodium plants, were established as serrat-14-en-3β, 21α, 24-triol (3), serrat-14-en-3β, 21β, 24-triol (36), and serrat-14-en-3α, 21β, 24-triol (22), respectively. The fourth possible stereoisomeric triol, serrat-14-en-3α, 21α, 24-triol (43), was prepared from lycoclavanol. New method of acetonide formation of 1, 3-glycol was reported.
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© The Pharmaceutical Society of Japan
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