Organic adhesives used for exterior wall tiling are considered to deteriorate when used outdoors because they are organic materials. Therefore, in this study, we devised the basic performance of the organic adhesive method and a heat and cool cycling test that accelerates the deterioration of the organic adhesive, and verified its long-term durability. Considering the various conditions under which organic adhesives are used, the tests were carried out by combining bases, base treatments, and organic adhesives. In addition, an outdoor exposure test was also conducted to examine the relationship with the heat and cool cycling test.