Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Notes
Separation of Polychlorinated Biphenyls from Mineral Oil Using Alkylammonium Ion-Bonded Silica Stationary Phases
Masahiko NUMATAYoshie AOYAGIYoko TSUDATakashi YARITAAkiko TAKATSU
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ジャーナル フリー

2006 年 22 巻 5 号 p. 785-788

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The potential of alkylammonium ion-bonded silica stationary phases for effective and simple pretreatment for determination of polychlorinated biphenyls (PCBs) in mineral oil samples is presented in this paper. The separation between PCBs and aliphatic hydrocarbons by normal phase chromatography was improved by using the alkylammonium ion-bonded silica stationary phases instead of alkylamine-bonded silica or other polar stationary phases. The number of alkyl residues bonded to the nitrogen atom was also an important factor of the separation.
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© 2006 by The Japan Society for Analytical Chemistry
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