Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Rapid Communications
Experimental Investigations of Trimer Ion Contributions in the Low Resolution Mass Spectrometry of Hydrogen Isotope Mixtures
Nicolae BIDICA
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2012 年 28 巻 11 号 p. 1033-1035

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This paper reports on some preliminary experimental results of a work in progress regarding a problem involving the quantitative analysis of hydrogen isotopes by mass spectrometry of low resolution: the triatomic (trimer) ions interferences with the isotopic hydrogen species having the same mass/charge. These results indicate that, in complex mixtures of hydrogen isotopes, trimer ions are strongly affected by the presence of other species, and a new approach that takes into account the destruction mechanism of trimer ions is necessary for a proper determination of their contributions.
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© 2012 by The Japan Society for Analytical Chemistry
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