Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Original Papers
A Selective, Colorimetric and Ratiometric Chemosensor for Hg2+ and Its Application as Test Papers
Hongwei ZHOUWei TIANMin JIANGPeng LIShihao ZENGWeixing CHENAijie MA
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JOURNAL FREE ACCESS

2015 Volume 31 Issue 12 Pages 1285-1289

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Abstract
Chemosensors provide an efficient and low-cost approach to the detection of various metal ions and small molecules. In the present work, we present a detailed investigation of a simple, easily-prepared, yet efficient, coumarin-based sensor for Hg2+. The sensor is based on a fluorescent group of coumarin. When exposed to Hg2+, the sensor solution shows a significant color change from yellow to red, and a fluorescence change from green to orange. Further study revealed that the sensor responds solely to Hg2+, and shows excellent selectivity even in the presence of other potential competition metal ions, including Na+, K+, Co2+, Fe2+, Cd2+, Cu2+, Ni2+, Ag+, Zn2+, Mg2+, Mn2+, Pb2+, Fe3+. Furthermore, the sensor has been successfully applied to detect Hg2+ in a form of test paper, which may promote easy and effective application of the sensor.
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© 2015 by The Japan Society for Analytical Chemistry
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