Lipase-catalyzed Kinetic Resolution of (±)-cis,cis-Spiro[4.4]nonane-1,6-diol

Yoshitaka MATSUSHIMA; Takeshi KITAHARA; Kenji MORI

doi:10.1271/bbb.62.1435

Bioscience, Biotechnology, and Biochemistry

Online ISSN : 1347-6947
Print ISSN : 0916-8451

Organic Chemistry Notes

Lipase-catalyzed Kinetic Resolution of (±)-cis,cis-Spiro[4.4]nonane-1,6-diol

Yoshitaka MATSUSHIMA, Takeshi KITAHARA, Kenji MORI

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Keywords: lipase-catalyzed kinetic resolution, cis,cis-spiro[4.4]nonane-1,6-diol, axial chirality, enantioselective esterification

JOURNAL FREE ACCESS

1998 Volume 62 Issue 7 Pages 1435-1437

DOI https://doi.org/10.1271/bbb.62.1435

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Abstract

(±)-cis,cis-Spiro[4.4]nonane-1,6-diol (1), which has axial chirality, was efficiently resolved by lipase-catalyzed enantioselective esterification in diisopropyl ether.

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