Absolute Configuration of a Ceramide with a Novel Branched-chain Fatty Acid Isolated from the Epiphytic Dinoflagellate, Coolia monotis

Kazuaki AKASAKA; Seiya SHICHIJYUKARI; Shigeru MATSUOKA; Michio MURATA; Hiroshi MEGURO; Hiroshi OHRUI

doi:10.1271/bbb.64.1842

Analytical Chemistry Regular Paper

Absolute Configuration of a Ceramide with a Novel Branched-chain Fatty Acid Isolated from the Epiphytic Dinoflagellate, Coolia monotis

Kazuaki AKASAKA, Seiya SHICHIJYUKARI, Shigeru MATSUOKA, Michio MURATA, Hiroshi MEGURO, Hiroshi OHRUI

著者情報

キーワード: absolute configuration, chiral discrimination, branched-chain fatty acid, chiral conversion reagent

ジャーナルフリー

2000 年 64 巻 9 号 p. 1842-1846

DOI https://doi.org/10.1271/bbb.64.1842

詳細

抄録

The absolute configuration of the chiral center at the C15 position of a novel branched-chain fatty acid derived from a new ceramide isolated from the epiphytic dinoflagellate Coolia monotis was determined to be of R from by reversed-phase HPLC after cleavage to 12-methylpentadecanoic acid and subsequent conversion with the chiral fluorescent reagent, (1R,2R)-2-(2,3-anthracenedicarboximido)cyclohexanol.

責任著者(Corresponding author)

J-STAGEへの登録はこちら（無料）