Synthesis of FF8181-A

Noriaki KOBAYASHI; Hidenobu KUNIYOSHI; Ken ISHIGAMI; Hidenori WATANABE

doi:10.1271/bbb.80351

Bioscience, Biotechnology, and Biochemistry

Online ISSN : 1347-6947
Print ISSN : 0916-8451

Organic Chemistry Regular Papers

Synthesis of FF8181-A

Noriaki KOBAYASHI, Hidenobu KUNIYOSHI, Ken ISHIGAMI, Hidenori WATANABE

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Keywords: FF8181-A, β-catenin, Diels-Alder reaction, optical resolution

JOURNAL FREE ACCESS

2008 Volume 72 Issue 10 Pages 2708-2715

DOI https://doi.org/10.1271/bbb.80351

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Abstract

Both enantiomers of FF8181-A were synthesized through optical resolution from the known Diels-Alder reaction product in 15 steps. The absolute configuration of the natural product was determined to be 1S,5S,5aS,9aS,9bS.

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