Conversion of Dechlorodauricumine into Miharumine by a Cell-Free Preparation from Cultured Roots of Menispermum dauricum

Rieko HORI; Gen SUGIMOTO; Miharu MATSUI; Yasuo YAMAUCHI; Hirosato TAKIKAWA; Yukihiro SUGIMOTO

doi:10.1271/bbb.80596

Organic Chemistry Note

Conversion of Dechlorodauricumine into Miharumine by a Cell-Free Preparation from Cultured Roots of Menispermum dauricum

Rieko HORI, Gen SUGIMOTO, Miharu MATSUI, Yasuo YAMAUCHI, Hirosato TAKIKAWA, Yukihiro SUGIMOTO

著者情報

キーワード: Menispermum dauricum, dechlorodauricumine, dehydrogenation, miharumine, N-demethylation

ジャーナルフリー

2009 年 73 巻 2 号 p. 440-442

DOI https://doi.org/10.1271/bbb.80596

View "Advance Publication" version (February 7, 2009).

詳細

抄録

Dechlorodauricumine (5) and dechloroacutumine (6) were converted to miharumine (7) and dechloroacutumidine (8), respectively, by a cell-free preparation from cultured roots of Menispermum dauricum in the presence of FAD. The structures of 7 and 8 were elucidated on the basis of spectroscopic analyses and chemical conversion.

責任著者(Corresponding author)

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