Bioscience, Biotechnology, and Biochemistry
Online ISSN : 1347-6947
Print ISSN : 0916-8451
Organic Chemistry Notes
Efficient Incorporation of Free Oxygen into Volicitin in Spodoptera litura Common Cutworm Larvae
Chihiro ISHIKAWANaoko YOSHINAGATakako ABOSHIRitsuo NISHIDANaoki MORI
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2009 年 73 巻 8 号 p. 1883-1885

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Volicitin [N-(17-hydroxylinolenoyl)-L-glutamine] has previously been identified from the lepidopteran larval regurgitant as an elicitor of plant volatile emission. The efficient incorporation of free oxygen into volicitin by Spodoptera litura larvae is demonstrated here by rearing them under 18O2 for three days. 18O-labeling of the hydroxyl group of volicitin was confirmed by liquid chromatography/mass spectrometry-ion trap-time-of-flight (LC/MS-IT-TOF) and suggests the activity of a monooxygenase in volicitin biosynthesis.
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© 2009 by Japan Society for Bioscience, Biotechnology, and Agrochemistry
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