Bioscience, Biotechnology, and Biochemistry
Online ISSN : 1347-6947
Print ISSN : 0916-8451
Organic Chemistry Notes
Enantioselective Synthesis of Aspergillide B
Tomohiro NAGASAWA, Shigefumi KUWAHARA
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Keywords: aspergillide, cytotoxic, macrolide, enantioselective synthesis
JOURNAL FREE ACCESS

2009 Volume 73 Issue 8 Pages 1893-1894

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Abstract
The enantioselective synthesis of aspergillide B, a 14-membered macrocyclic cytotoxin, was achieved in a 49% yield via 7 steps from a synthetic intermediate of aspergillide C. The spectroscopic data and specific rotation value for the synthetic material matched those of natural aspergillide B.
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© 2009 by Japan Society for Bioscience, Biotechnology, and Agrochemistry
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