Agricultural and Biological Chemistry
Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369
Reactions between Organophosphates and Organomercurials
Hiroshi KUBOIchiro MUTAOsami MATANORokuro SATO
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1961 Volume 25 Issue 2 Pages 144-150

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Abstract
Our interest in the preparation of a new type of biologically active substances led us to investigate the reaction between organophosphates and organomercurials. O-Arylmercuric O, O-dialkyl thiophosphates (I) were synthesized by several methods from arylmercuric chloride and O, O-dialkyl thiophosphate in the presence of silver. Likewise several approaches to the synthesis of arylmercuric dialkyl thiophosphate (II) were made. Dialkyldithiophosphate and organomercurial reacted readily in several organic solvents to yield mercury bis (dialkyl dithiophosphate)(IV).
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