Agricultural and Biological Chemistry
Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369
Microbial Resolution of Racemic 2- and 3-Alkylcyclohexanols
Takayuki ORITANIKyohei YAMASHITA
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1973 年 37 巻 7 号 p. 1695-1700

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By using microorganisms (their esterase), (±)-trans and cis-2-methylcyclohexyl acetates were asymmetrically hydrolyzed to (-)-traps-2-methylcyclohexanol with (+)-trans-2-methylcyclohexyl acetate and (-)-cis-2-methylcyclohexanol with (+)-cis-2-methylcyclohexyl acetate. Similarly (±)-traps and cis-3-methylcyclohexyl acetates were hydrolyzed by the same microorganisms to give (+)-trans-3-methylcyclohexanol with (-)-tians-3-methylcyclohexyl acetate and (-)-cis-3-methylcyclohexanol with (+)-cis-3-methylcyclohexyl acetate.
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© Japan Society for Bioscience, Biotechnology, and Agrochemistry
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